Evaluation of Standard Changes in Enthalpy During Complex Formation of Mn(II), Ni(II), Cd(II) and Hg(II) with p-fluorobenzoylthioacetophenone
Downloads
Published
DOI:
https://doi.org/10.58414/SCIENTIFICTEMPER.2022.13.2.24Keywords:
Enthalpy, Monothio-β-diketones, Overall Stability Constant, p-fluorobenzoylthioacetophenone, Solution EquilibriaDimensions Badge
Issue
Section
License
Copyright (c) 2022 The Scientific Temper
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
The stability constant values of the complexes of p-fluorobenzoylthioacetophenone with bivalent manganese, nickel, cadmium and mercury at different temperatures viz. 283K, 293K and 303K have been determined using Calvin-Bjerrum’s pH titration technique as adopted by Irving and Rossotti. Standard change in free energy at desired temperatures were evaluated with the help of data of overall stability constants using the thermodynamic expression, ΔG° = −2.303 RT Log β. The standard changes in enthalpy associated with the complex formation reactions were evaluated with the help of Isobar equation. The standard enthalpy change was also calculated by using Gibbs-Helmholtz equation. From values obtained, the standard changes in enthalpy associated with the above complex formation have been thoroughly discussed.Abstract
How to Cite
Downloads
Similar Articles
- Nitin Chandel, Lalsingh Khalsa, Sunil Prayagi, Vinod Varghese, Three‑phase‑lags thermoelastic infinite medium model with a spherical cavity via memory-dependent derivatives , The Scientific Temper: Vol. 15 No. 01 (2024): The Scientific Temper
- V. Parimala, D. Ganeshkumar, Solar energy-driven water distillation with nanoparticle integration for enhanced efficiency, sustainability, and potable water production in arid regions , The Scientific Temper: Vol. 15 No. 01 (2024): The Scientific Temper
- C. S. Manikandababu, V. Rukkumani, Advanced VLSI-based digital image contrast enhancement: A novel approach with modified image pixel evaluation logic , The Scientific Temper: Vol. 15 No. 01 (2024): The Scientific Temper
- R. Porselvi, D. Kanchana, Beulah Jackson, L. Vigneash, Dynamic resource management for 6G vehicular networks: CORA-6G offloading and allocation strategies , The Scientific Temper: Vol. 15 No. 02 (2024): The Scientific Temper
- Ellakkiya Mathanraj, Ravi N. Reddy, Enhanced principal component gradient round-robin load balancing in cloud computing , The Scientific Temper: Vol. 15 No. 01 (2024): The Scientific Temper
- AMIR ALI, PERWEZ AHMAD, STUDIES ON TOTAL PLASMA VOLUME, CORPUSCULAR VOLUME AND BLOOD WEIGHT IN RELATION TO BODY WEIGHT IN A FRESH WATER TELEOSTEAN FISH MYSTUS CAVASIUS (HAM.) , The Scientific Temper: Vol. 10 No. 1&2 (2019): The Scientific Temper
- Rama Rao J.V.G, Raja Gopal A.N.V.J, Ponnaganti S. Prasad, Illa V. Ram, Muthuvel B, Power quality improvement in BLDC motor drive using PFC converter , The Scientific Temper: Vol. 14 No. 04 (2023): The Scientific Temper
- Pavithra M, Dr. R. Neelaveni, Muthuraman K. R , Kamalesh G, Design of an interactive smart band for intellectually disabled person , The Scientific Temper: Vol. 14 No. 02 (2023): The Scientific Temper
You may also start an advanced similarity search for this article.
Most read articles by the same author(s)
- Hashmat Ali, Nishant Soren, Rohit Kumar Ravi, Kunal Kumar, Anjali, Evaluation of Standard Changes in Free Energy During Complexation of p-chlorobenzoylthioacetophenone with Some Bivalent Transition Metals , The Scientific Temper: Vol. 13 No. 02 (2022): The Scientific Temper
